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Air Quality Sensor

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calibrationaqigas sensorhchoair quality
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  • supersjimmieS supersjimmie

    @epierre I am testing a stripped-down version of your code from your AirQuality-MQ135.ino. I stripped it to make it run just stand-alone.
    What I don't understand is how to do the calibration. When I run it in outside environment (with 10k resistor), I get these values:

    valr 223
    Vrl / Rs / ratio:13387 / 20875.00 / 0.00
    

    What would be the next step for calibration?

    epierreE Offline
    epierreE Offline
    epierre
    Hero Member
    wrote on last edited by
    #138

    @supersjimmie replace MQ135_DEFAULTRO by your value 20875 in the sketch

    z-wave - Vera -> Domoticz
    rfx - Domoticz <- MyDomoAtHome <- Imperihome
    mysensors -> mysensors-gw -> Domoticz

    supersjimmieS 1 Reply Last reply
    0
    • epierreE epierre

      @supersjimmie replace MQ135_DEFAULTRO by your value 20875 in the sketch

      supersjimmieS Offline
      supersjimmieS Offline
      supersjimmie
      wrote on last edited by supersjimmie
      #139

      @epierre Thanks, I thought it would be something like that, but that didn't work.
      I then got

      valr 242
      Vrl / Rs / ratio:5464 / 8520.00 / 0.00
      

      Nothing like around 400ppm.

      1 Reply Last reply
      0
      • epierreE Offline
        epierreE Offline
        epierre
        Hero Member
        wrote on last edited by
        #140

        yes for the code must be updated, the value is the CO2 (or something else) detected above the 399 in atmosphere

          gw.send(msg.set(MQ135_DEFAULTPPM+(int)ceil(valAIQ)));
        

        z-wave - Vera -> Domoticz
        rfx - Domoticz <- MyDomoAtHome <- Imperihome
        mysensors -> mysensors-gw -> Domoticz

        1 Reply Last reply
        0
        • supersjimmieS Offline
          supersjimmieS Offline
          supersjimmie
          wrote on last edited by
          #141

          Thanks, but when calibrating something strange happens when I put the module outside:

          valr 270
          Vrl   / Rs       / ratio  / ppm
          61355 / 95673.00 / 0.00 / 399.00
          valr 265
          Vrl   / Rs       / ratio  / ppm
          62928 / 98126.00 / 0.00 / 399.00
          valr 260
          Vrl   / Rs       / ratio  / ppm
          64561 / 100673.00 / 0.00 / 399.00
          valr 256
          Vrl   / Rs       / ratio  / ppm
          378 / 589.00 / 0.00 / 399.00
          valr 252
          Vrl   / Rs       / ratio  / ppm
          1773 / 2764.00 / 0.00 / 399.00
          

          As you can see, the valr decreases slowly, but suddenly Vlr and Rs jump over.
          Vlr is the value of 'val', which is: uint16_t val = ((float)22000*(1023-valr)/valr);
          uint16_t is 16bit, so max 65535. It looks like my environment needs more than that?
          (in fact, your code defines the defaultro as 68550, which is also too much for a uint16?)

          epierreE 1 Reply Last reply
          0
          • supersjimmieS supersjimmie

            Thanks, but when calibrating something strange happens when I put the module outside:

            valr 270
            Vrl   / Rs       / ratio  / ppm
            61355 / 95673.00 / 0.00 / 399.00
            valr 265
            Vrl   / Rs       / ratio  / ppm
            62928 / 98126.00 / 0.00 / 399.00
            valr 260
            Vrl   / Rs       / ratio  / ppm
            64561 / 100673.00 / 0.00 / 399.00
            valr 256
            Vrl   / Rs       / ratio  / ppm
            378 / 589.00 / 0.00 / 399.00
            valr 252
            Vrl   / Rs       / ratio  / ppm
            1773 / 2764.00 / 0.00 / 399.00
            

            As you can see, the valr decreases slowly, but suddenly Vlr and Rs jump over.
            Vlr is the value of 'val', which is: uint16_t val = ((float)22000*(1023-valr)/valr);
            uint16_t is 16bit, so max 65535. It looks like my environment needs more than that?
            (in fact, your code defines the defaultro as 68550, which is also too much for a uint16?)

            epierreE Offline
            epierreE Offline
            epierre
            Hero Member
            wrote on last edited by
            #142

            @supersjimmie said:

            Vlr is the value of 'val', which is: uint16_t val = ((float)22000*(1023-valr)/valr);

            yes and this is why I did rewrite it to https://github.com/empierre/arduino/blob/master/AirQuality-Multiple_Gas_Sensor1_4.ino but did not updated this one...

            z-wave - Vera -> Domoticz
            rfx - Domoticz <- MyDomoAtHome <- Imperihome
            mysensors -> mysensors-gw -> Domoticz

            supersjimmieS 1 Reply Last reply
            0
            • epierreE epierre

              @supersjimmie said:

              Vlr is the value of 'val', which is: uint16_t val = ((float)22000*(1023-valr)/valr);

              yes and this is why I did rewrite it to https://github.com/empierre/arduino/blob/master/AirQuality-Multiple_Gas_Sensor1_4.ino but did not updated this one...

              supersjimmieS Offline
              supersjimmieS Offline
              supersjimmie
              wrote on last edited by supersjimmie
              #143

              @epierre I striped-down that AirQuality-Multiple_Gas_Sensor1_4.ino to use only MQ135.
              When used inside, the analogRead is 473, so a reasonble value.
              But the MQCalibration function returns 0. Which means the MQResistanceCalculation also returns 0.

              MQResistenceCalculation only does one calc:
              return (long)((long)(1024 * 1000 * (long)rl_value)/raw_adc-(long)rl_value);
              rl_value = float RL4 = 0.990
              raw_adc = 473 (measured as said above)
              (1024 * 1000 * 0.990) / 473 - 0.990 = 2142.266
              I checked that raw_adc is filled with the correct value (to be sure it is not lost somewhere).

              What looks to fix this, I changed everything to float . So:
              return (float)((float)(1024 .* 1000. * (float)rl_value)/raw_adc-(float)rl_value);
              Which can be simplyfied as:
              return ((1024 * 1000*rl_value)/raw_adc-rl_value);
              I went to float, because the function is created as float MQResistenceCalculation.

              This now gives some ppm values that are within a reasonable range (about 2000 here).

              Now I have to figure out how to do calibration on this method again...

              1 Reply Last reply
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              • epierreE Offline
                epierreE Offline
                epierre
                Hero Member
                wrote on last edited by
                #144

                looks like I have to rework something... but not in the todo list right now... Imperihome is now back on top, and Particle on lipo/solar also...

                z-wave - Vera -> Domoticz
                rfx - Domoticz <- MyDomoAtHome <- Imperihome
                mysensors -> mysensors-gw -> Domoticz

                1 Reply Last reply
                0
                • tantt2810T Offline
                  tantt2810T Offline
                  tantt2810
                  wrote on last edited by
                  #145

                  Hello,
                  I don't know how to calculate 3 numbers of LPGCurve[]. Can you explain clearly for me? Thank you so much !!!

                  0_1456336543192_Capture.PNG

                  1 Reply Last reply
                  0
                  • epierreE Offline
                    epierreE Offline
                    epierre
                    Hero Member
                    wrote on last edited by
                    #146

                    @tantt2810 as explained above, if the datasheet has a logarithmic scale, you can use the power regression to approximate the curve. One tool for example to do this calculus:http://www.xuru.org/rt/powr.asp

                    for a sensor discussed above I read this on the datasheet:
                    H2
                    1.3 50
                    0.8 100
                    0.28 400
                    0.16 1000
                    0.05 4000

                    The xuru website gives me this:

                    y = 73.59123879 x-1.355617483
                    Residual Sum of Squares: rss = 87393.44418

                    and thus I have::
                    H2Curve[3] = {73.5912, -1.355617};

                    z-wave - Vera -> Domoticz
                    rfx - Domoticz <- MyDomoAtHome <- Imperihome
                    mysensors -> mysensors-gw -> Domoticz

                    tantt2810T 1 Reply Last reply
                    0
                    • epierreE epierre

                      @tantt2810 as explained above, if the datasheet has a logarithmic scale, you can use the power regression to approximate the curve. One tool for example to do this calculus:http://www.xuru.org/rt/powr.asp

                      for a sensor discussed above I read this on the datasheet:
                      H2
                      1.3 50
                      0.8 100
                      0.28 400
                      0.16 1000
                      0.05 4000

                      The xuru website gives me this:

                      y = 73.59123879 x-1.355617483
                      Residual Sum of Squares: rss = 87393.44418

                      and thus I have::
                      H2Curve[3] = {73.5912, -1.355617};

                      tantt2810T Offline
                      tantt2810T Offline
                      tantt2810
                      wrote on last edited by
                      #147

                      @epierre Thank you so much !!!
                      Have a nice day =)) !!!

                      1 Reply Last reply
                      0
                      • epierreE epierre

                        So tonight with these new formulae, I updated my mega sketch to get :

                         MQ2    :LPG   :0ppm    CO    :0ppm    SMOKE :0ppm
                         MQ6    :LPG   :0ppm    CH4   :0ppm
                         MQ131  :CL2   :1ppm    O3    :1ppm
                         TGS2600:H2    :0ppm    C2H5OH:0ppm    C4H10 :0ppm
                        

                        Going through the "clean air calibation" I have:

                        float MQResistanceCalculation(int raw_adc)    {
                          return ( ((float)RL_VALUE*(1023-raw_adc)/raw_adc));
                        }
                        

                        Here are the readings without:

                        MQ2:5.28
                        MQ6:36.94
                        MQ131:3.61
                        TGS2600:0.04
                        

                        and with all is 0... BTW...

                        What do you think of that ? nothing indicated that MQ6 should be so big, and tgs so low... same for MQ131 that should be 100k-200k per datasheet....

                        jenbakerJ Offline
                        jenbakerJ Offline
                        jenbaker
                        wrote on last edited by
                        #148

                        @epierre

                        hi

                        i am new here.

                        sorry i am a little confused by with these new formulate.

                        is it the key for module?

                        epierreE 1 Reply Last reply
                        0
                        • tantt2810T Offline
                          tantt2810T Offline
                          tantt2810
                          wrote on last edited by
                          #149

                          Hello,
                          I'm don't understand the recipe below. Why RL_Value(Load Resistance)(1023-raw_adc)/raw_adc)? Can you explain for me?
                          Thank you so much !!!
                          /
                          ***************** MQResistanceCalculation ****************************************
                          Input: raw_adc - raw value read from adc, which represents the voltage
                          Output: the calculated sensor resistance
                          Remarks: The sensor and the load resistor forms a voltage divider. Given the voltage
                          across the load resistor and its resistance, the resistance of the sensor
                          could be derived.
                          ***********************************************************************************/
                          float MQ2::MQResistanceCalculation(int raw_adc)
                          {
                          return ( ((float)RL_VALUE
                          (1023-raw_adc)/raw_adc));
                          }

                          epierreE 1 Reply Last reply
                          0
                          • jenbakerJ jenbaker

                            @epierre

                            hi

                            i am new here.

                            sorry i am a little confused by with these new formulate.

                            is it the key for module?

                            epierreE Offline
                            epierreE Offline
                            epierre
                            Hero Member
                            wrote on last edited by
                            #150

                            @jenbaker said:

                            sorry i am a little confused by with these new formulate.

                            is it the key for module?

                            if you have a module the datasheet gives you the values, yes. Remember this is their """""generic"""" calibration, in fact they all copy the other so don't expect your MQ** would follow this by the letter...

                            z-wave - Vera -> Domoticz
                            rfx - Domoticz <- MyDomoAtHome <- Imperihome
                            mysensors -> mysensors-gw -> Domoticz

                            1 Reply Last reply
                            0
                            • tantt2810T tantt2810

                              Hello,
                              I'm don't understand the recipe below. Why RL_Value(Load Resistance)(1023-raw_adc)/raw_adc)? Can you explain for me?
                              Thank you so much !!!
                              /
                              ***************** MQResistanceCalculation ****************************************
                              Input: raw_adc - raw value read from adc, which represents the voltage
                              Output: the calculated sensor resistance
                              Remarks: The sensor and the load resistor forms a voltage divider. Given the voltage
                              across the load resistor and its resistance, the resistance of the sensor
                              could be derived.
                              ***********************************************************************************/
                              float MQ2::MQResistanceCalculation(int raw_adc)
                              {
                              return ( ((float)RL_VALUE
                              (1023-raw_adc)/raw_adc));
                              }

                              epierreE Offline
                              epierreE Offline
                              epierre
                              Hero Member
                              wrote on last edited by
                              #151

                              @tantt2810 said:

                              Hello,
                              I'm don't understand the recipe below. Why RL_Value(Load Resistance)(1023-raw_adc)/raw_adc)? Can you explain for me?
                              Thank you so much !!!
                              Input: raw_adc - raw value read from adc, which represents the voltage
                              Output: the calculated sensor resistance
                              Remarks: The sensor and the load resistor forms a voltage divider. Given the voltage
                              across the load resistor and its resistance, the resistance of the sensor
                              could be derived.
                              float MQ2::MQResistanceCalculation(int raw_adc)
                              RL_VALUE
                              (1023-raw_adc)/raw_adc));

                              in fact it is above described, you have a voltage, you want a resistance.
                              https://learn.sparkfun.com/tutorials/voltage-dividers

                              datasheet needs a value which is the Rs/Ro (called here RL) where
                              Ro: sensor resistance at 100ppm of NH3 in the clean air.
                              Rs:sensor resistance at various concentrations of gases

                              here the formula is a simplification of this:

                              float Vrl = val * ( 5.00 / 1024.0 ); // V
                              float Rs = 20000 * ( 5.00 - Vrl) / Vrl ; // Ohm
                              int ratio = Rs/Ro;
                              ppm = 37143 * pow (ratio, -3.178);

                              z-wave - Vera -> Domoticz
                              rfx - Domoticz <- MyDomoAtHome <- Imperihome
                              mysensors -> mysensors-gw -> Domoticz

                              tantt2810T VirV 2 Replies Last reply
                              1
                              • epierreE epierre

                                @tantt2810 said:

                                Hello,
                                I'm don't understand the recipe below. Why RL_Value(Load Resistance)(1023-raw_adc)/raw_adc)? Can you explain for me?
                                Thank you so much !!!
                                Input: raw_adc - raw value read from adc, which represents the voltage
                                Output: the calculated sensor resistance
                                Remarks: The sensor and the load resistor forms a voltage divider. Given the voltage
                                across the load resistor and its resistance, the resistance of the sensor
                                could be derived.
                                float MQ2::MQResistanceCalculation(int raw_adc)
                                RL_VALUE
                                (1023-raw_adc)/raw_adc));

                                in fact it is above described, you have a voltage, you want a resistance.
                                https://learn.sparkfun.com/tutorials/voltage-dividers

                                datasheet needs a value which is the Rs/Ro (called here RL) where
                                Ro: sensor resistance at 100ppm of NH3 in the clean air.
                                Rs:sensor resistance at various concentrations of gases

                                here the formula is a simplification of this:

                                float Vrl = val * ( 5.00 / 1024.0 ); // V
                                float Rs = 20000 * ( 5.00 - Vrl) / Vrl ; // Ohm
                                int ratio = Rs/Ro;
                                ppm = 37143 * pow (ratio, -3.178);

                                tantt2810T Offline
                                tantt2810T Offline
                                tantt2810
                                wrote on last edited by
                                #152

                                @epierre Hi you,
                                I think the Rs/Ro is not RL. In the datasheet RL=5kOhm. As I know it is a resistance on board Arduino, and we set it 5kOhm. Is it right? I also don't know why we set it equal 5kOhm. =))
                                And why 20000 is in "float Rs = 20000 * ( 5.00 - Vrl) / Vrl ; // Ohm" ?
                                Please help me clearly. Thank you so much !!!

                                1 Reply Last reply
                                0
                                • tantt2810T Offline
                                  tantt2810T Offline
                                  tantt2810
                                  wrote on last edited by
                                  #153

                                  Hello,
                                  I have read the sensitivity characteristics curve in datasheet of MQ135 and I don't know AL R, 3/4, 1/4* and +- mean? Can you help me, please !!!
                                  NH4 represent for NH3, doesn't it ?
                                  Thank you so much !!!

                                  1 Reply Last reply
                                  0
                                  • tantt2810T Offline
                                    tantt2810T Offline
                                    tantt2810
                                    wrote on last edited by
                                    #154

                                    Hi everyone,
                                    I have an CO2 MG811 sensor. I don't know where tcm pin connect with ?
                                    Please help me. Thank you so much !!!!
                                    0_1457101257425_F08406-CO2-Carbon-Dioxide-Sensor-Module-font-b-MG811-b-font-Voltage-0-2V-Voltage-Output.jpg

                                    epierreE 1 Reply Last reply
                                    0
                                    • TFPOK1T Offline
                                      TFPOK1T Offline
                                      TFPOK1
                                      wrote on last edited by
                                      #155

                                      Hello, I'm working with an MQ-136 sensor, and am interested in measuring H2S and/or SO2 concentrations. I've got a simple sketch written which gives me a fairly consistent value on the serial monitor, but I've tried to run the multiple gas sensor sketch both complete and I also tried picking apart the sketch just to include MQ-136 related variables and algorithms, but I can't get it to work. It's showing too many errors to list here. Does anyone have simple conversions from the serial outputs to usable values for various gases that this sensor can measure?

                                      1 Reply Last reply
                                      0
                                      • Joel PérezJ Offline
                                        Joel PérezJ Offline
                                        Joel Pérez
                                        wrote on last edited by
                                        #156

                                        hello, how i read co2 ppm with my mq135?
                                        helpme please

                                        1 Reply Last reply
                                        0
                                        • tantt2810T tantt2810

                                          Hi everyone,
                                          I have an CO2 MG811 sensor. I don't know where tcm pin connect with ?
                                          Please help me. Thank you so much !!!!
                                          0_1457101257425_F08406-CO2-Carbon-Dioxide-Sensor-Module-font-b-MG811-b-font-Voltage-0-2V-Voltage-Output.jpg

                                          epierreE Offline
                                          epierreE Offline
                                          epierre
                                          Hero Member
                                          wrote on last edited by
                                          #157

                                          @tantt2810 said:

                                          Hi everyone,
                                          I have an CO2 MG811 sensor. I don't know where tcm pin connect with ?
                                          Please help me. Thank you so much !!!!

                                          this is an analogic sensor, so VCC/Gnd to power it, and readings on analogic Aout

                                          z-wave - Vera -> Domoticz
                                          rfx - Domoticz <- MyDomoAtHome <- Imperihome
                                          mysensors -> mysensors-gw -> Domoticz

                                          tantt2810T 1 Reply Last reply
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