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Air Quality Sensor

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calibrationaqigas sensorhchoair quality
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  • korttomaK korttoma

    Now changed my sensor according to this (disconnected the OP related to DOUT) :
    upload-94e081f9-006e-4d91-b736-3f82ef8e119b

    Please confirm that this is how it is preferred to be connected.

    epierreE Offline
    epierreE Offline
    epierre
    Hero Member
    wrote on last edited by epierre
    #76

    @korttoma I have found a sketch that may interrest you about the gas sensors boards:

    http://www.parallax.com/sites/default/files/downloads/27983-Gas-Sensor-Board-A-Schematic.pdf

    Their document speaks also about calibrating some gases:
    http://www.parallax.com/sites/default/files/downloads/27983-Gas-Sensor-Board-Guide-v1.0.pdf

    z-wave - Vera -> Domoticz
    rfx - Domoticz <- MyDomoAtHome <- Imperihome
    mysensors -> mysensors-gw -> Domoticz

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    • epierreE epierre

      @Yveaux you mean something like this ?

      return ( (((float)RL_VALUE*(1023.0 - (float) raw_adc)) / (float) raw_adc));
      

      I somehow forked the discussion on arduino.cc and sent an email in parallel do Davide Gironi for I would like to understand his formula as opposed to the curve approach.

      epierreE Offline
      epierreE Offline
      epierre
      Hero Member
      wrote on last edited by
      #77

      @Yveaux I have doubts about calculing the resistance, for it is depending on the steps, either 1024 or 4096, and/or the voltage either 5V or 3.3V.

      I started with this formulae:

      return ( ((float)RL_VALUE*(1023-raw_adc)/raw_adc));
      

      But saw Davide Gironi using this one:

      return  (long)((long)(1024*(long)RL_VALUE)/raw_adc-(long)RL_VALUE);
      

      RL_VALUE=22000

      z-wave - Vera -> Domoticz
      rfx - Domoticz <- MyDomoAtHome <- Imperihome
      mysensors -> mysensors-gw -> Domoticz

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      • epierreE Offline
        epierreE Offline
        epierre
        Hero Member
        wrote on last edited by
        #78

        @Yveaux @korttoma
        Bummer... this is the same formula when doing the reduction.... one is 1023 the other 1024 the only change.

        The RL_VALUE for Davide was 22k, when I mesure the resistance with Analog out with ground, I get 0,996 or 0,999 ohms depending on the sensor. I guess this is the RL_VALUE of the board which is way below the sensor maker recommendation (between 10K and 47K for a MQ135).

        Also, I saw that the pot on the board does not change the analog to ground resistance, meaning it is used only for comparison of the digital output....

        Am I correct in mesuring this ?

        z-wave - Vera -> Domoticz
        rfx - Domoticz <- MyDomoAtHome <- Imperihome
        mysensors -> mysensors-gw -> Domoticz

        YveauxY 1 Reply Last reply
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        • epierreE epierre

          @Yveaux @korttoma
          Bummer... this is the same formula when doing the reduction.... one is 1023 the other 1024 the only change.

          The RL_VALUE for Davide was 22k, when I mesure the resistance with Analog out with ground, I get 0,996 or 0,999 ohms depending on the sensor. I guess this is the RL_VALUE of the board which is way below the sensor maker recommendation (between 10K and 47K for a MQ135).

          Also, I saw that the pot on the board does not change the analog to ground resistance, meaning it is used only for comparison of the digital output....

          Am I correct in mesuring this ?

          YveauxY Offline
          YveauxY Offline
          Yveaux
          Mod
          wrote on last edited by
          #79

          @epierre said:

          Also, I saw that the pot on the board does not change the analog to ground resistance, meaning it is used only for comparison of the digital output....

          That seems to match the schematic above where the pot connects to + of the lm393

          http://yveaux.blogspot.nl

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          • epierreE Offline
            epierreE Offline
            epierre
            Hero Member
            wrote on last edited by epierre
            #80

            @Yveaux Doing so, I have used a RL_VALUE for each board I mesured, one went to 5MOhms...

            MQ2:-8.85
            MQ6:0.00
            MQ131:0.00
            TGS2600:0.00
            MQ135:0.00
            2SH12:-155004.00
            TGZS2602:0.00
            

            Something to be noted: same boards have the same resistance, whatever the sensor maker recommendation, this is a pity...

            The output I have:

            MQ2    :LPG   :7ppm    CO    :0ppm    SMOKE :10ppm
            MQ6    :LPG   :0ppm    CH4   :0ppm
            MQ131  :CL2   :0ppm    O3    :0ppm
            TGS2600:H2    :0ppm    C2H5OH:0ppm C4H10 :0ppm
            MQ135  :CO2   :0ppm    CO    :0ppm     CH3   :0ppm    NH4    :0ppm
            2SH12  :SO2   :-154588.20 raw 
            TGS2602:C7H8  :0ppm
            Dust   :raw   : 0    Voltage: 0.00 - Dust Density: -0.10
            

            something to remember: MQ135 was calibrated for 1ppm of CO, not 399ppm of CO2, so the calculated value is very low, a per gas Ro must be calculated (clean air calibration) if several gas on one sensor is required to be displayed.

            z-wave - Vera -> Domoticz
            rfx - Domoticz <- MyDomoAtHome <- Imperihome
            mysensors -> mysensors-gw -> Domoticz

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            • epierreE Offline
              epierreE Offline
              epierre
              Hero Member
              wrote on last edited by
              #81

              Some interresting points from another discussion on the MQ138 that is given for HCHO.

              Historically a datasheet said so, but it is impossible to read the datasheet curves:
              http://china-total.com/Product/meter/gas-sensor/MQ138.pdf

              The latest ones do not speak of HCHO any more.

              An available alternative: grove is a wsp2110 and datasheet can be found.
              http://www.seeedstudio.com/wiki/Grove_-_HCHO_Sensor

              z-wave - Vera -> Domoticz
              rfx - Domoticz <- MyDomoAtHome <- Imperihome
              mysensors -> mysensors-gw -> Domoticz

              1 Reply Last reply
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              • A Offline
                A Offline
                alex
                wrote on last edited by
                #82

                Hello all,

                I'm new here, thanks to this topic very interesting for my personal project: a mobile air quality sensor.
                (sorry for my english, i'm french)

                Fistly, congrat's @epierre and the other, for having shared all this informations!
                (it's a litte funny because we had the same idea in the almost same time)
                So after having read the entire subject, here my questions (the number in front is the number post):

                _
                17 - @epierre, I haven't well understand How you can distinguish individual gas from a sensor who react with several gas.

                45 - The "Wunder Weather" list that you talked about, it's a website?

                55 - What David did you answer to you about "if he speaks of the organic sensor or the ceramic ones"?
                Moreover, what are the organic sensors? Have you example?

                72- On winsensor.com, an chinese gas sensor producer, the MQ-7 is more powerfull... I don't know who trust, maybe it's not the same?? See the PDF datasheet here.

                81 - Where did you read that the lastest one don't speak of HCHO anymore?
                After some research, I founded two, one who speak about HCHO here in english , and the other who don't....but I'm not sure (beacause in chinese) here.

                Otherwise, for the WSP2110 datasheet, it is here! But chinese too =/

                Regards,
                Alex.

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                • epierreE Offline
                  epierreE Offline
                  epierre
                  Hero Member
                  wrote on last edited by
                  #83

                  Hello,

                  This is a short post, half has been lost in a forum crash, I hope the best remains ;-)

                  17 - @epierre, I haven't well understand How you can distinguish individual gas from a sensor who react with several gas.
                  

                  You cannot as I showed below with the broken perfume bottle, you can guess there is one, but not which one.

                  45 - The "Wunder Weather" list that you talked about, it's a website?
                  

                  This is wunderground.com

                  55 - What David did you answer to you about "if he speaks of the organic sensor or the ceramic ones"?
                  Moreover, what are the organic sensors? Have you example?
                  

                  The organic are the one that have a lifetime of 2 years, calibrated but wery expensive (aroung $150+ apiece), the winseng one for example, big and round.

                  72- On winsensor.com, an chinese gas sensor producer, the MQ-7 is more powerfull... I don't know who trust, maybe it's not the same?? See the PDF datasheet here.
                  

                  this is hard to say... the MQ-7 is quite special with a sequence to power it up, and readings every period.

                  81 - Where did you read that the lastest one don't speak of HCHO anymore?
                  After some research, I found two, one who speak about HCHO here in english , and the other who don't....but I'm not sure (beacause in chinese) here.
                  

                  I don't see mention of HCHO (formaldehyde) in the english one (n-Hexane, Benzene, NH3, alcohol, ,smoke, CO. I found one in chinese with the link above but the curve couldn't be exploited. Please remark that Alcohool has not a single formula, but here they show only one curve, not very precise.

                  Otherwise, for the WSP2110 datasheet, it is here! But chinese too =/
                  

                  Yes for this one something can be done, but there is no for WSP1110 there is no...

                  z-wave - Vera -> Domoticz
                  rfx - Domoticz <- MyDomoAtHome <- Imperihome
                  mysensors -> mysensors-gw -> Domoticz

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                  • A Offline
                    A Offline
                    alex
                    wrote on last edited by alex
                    #84

                    Ok! Thanks.

                    And what about the ceramic sensors (like MQ serie). How long can we trust them?

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                    • epierreE Offline
                      epierreE Offline
                      epierre
                      Hero Member
                      wrote on last edited by
                      #85

                      @alex said:

                      Ok! Thanks.
                      And what about the ceramic sensors (like MQ serie). How long can we trust them?

                      a bit longer but they vary in time as Davide made the remark, so calibration is not one time in its life...

                      z-wave - Vera -> Domoticz
                      rfx - Domoticz <- MyDomoAtHome <- Imperihome
                      mysensors -> mysensors-gw -> Domoticz

                      1 Reply Last reply
                      0
                      • A Offline
                        A Offline
                        alex
                        wrote on last edited by alex
                        #86

                        Hello

                        @epierre : after received the PPD42NS, compared to the DSM501A, which one is the best do you think?

                        Other things, I planned to purchase soon the sensors that I need for my air station.
                        You made a list on the #1 post, and it's very useful thanks, but now I have to choose between them for each gas targeted (maybe some sensors are still missing on the list below)

                        Which one appears for you, the better for each gas, with a reasonable price?

                        O3		    MQ131   MICS-2610    Mics-2614
                        NO2 	      MiCS-2710    MiCS-2714
                        NO            ? 
                        PM10 PM2.5    PPD42NS    SamYoung DSM501
                        Benzene	   MQ135			
                        CO  	      MQ307A   MQ309A   AQ-7   MiCS-5525   TGS2442
                        So2 	      MQ136
                        COV       	MQ135  TGS2602
                        CO2 	      MQ135
                        
                        epierreE 1 Reply Last reply
                        0
                        • A alex

                          Hello

                          @epierre : after received the PPD42NS, compared to the DSM501A, which one is the best do you think?

                          Other things, I planned to purchase soon the sensors that I need for my air station.
                          You made a list on the #1 post, and it's very useful thanks, but now I have to choose between them for each gas targeted (maybe some sensors are still missing on the list below)

                          Which one appears for you, the better for each gas, with a reasonable price?

                          O3		    MQ131   MICS-2610    Mics-2614
                          NO2 	      MiCS-2710    MiCS-2714
                          NO            ? 
                          PM10 PM2.5    PPD42NS    SamYoung DSM501
                          Benzene	   MQ135			
                          CO  	      MQ307A   MQ309A   AQ-7   MiCS-5525   TGS2442
                          So2 	      MQ136
                          COV       	MQ135  TGS2602
                          CO2 	      MQ135
                          
                          epierreE Offline
                          epierreE Offline
                          epierre
                          Hero Member
                          wrote on last edited by
                          #87

                          @alex said:

                          @epierre : after received the PPD42NS, compared to the DSM501A, which one is the best do you think?

                          I currently have only the DSL501A working, many issues with the dead Shinyei (still in dispute escalade) and getting one from another seller takes so much time...

                          Which one appears for you, the better for each gas, with a reasonable price?
                          O3 MQ131 MICS-2610 Mics-2614
                          NO2 MiCS-2710 MiCS-2714
                          NO ?
                          PM10 PM2.5 PPD42NS SamYoung DSM501
                          Benzene MQ135
                          CO MQ307A MQ309A AQ-7 MiCS-5525 TGS2442
                          So2 MQ136
                          COV MQ135 TGS2602
                          CO2 MQ135

                          The price is low, but so is the result. Only the CO-MH-Z14 is calibrated. For all the others, there is the calibration issue.

                          See the sketch for a lit of known/tested sensors (some I don't have but a frien asked me for the curves so I added it to the Mega sketch)
                          https://github.com/empierre/arduino/blob/master/AirQuality-Multiple_Gas_Sensor1_4.ino

                          • The MiCS are problematic to find in Europe (!) so I have only one that I have not yet tested.
                          • The Figaro have been tested, but it is hard to know how to really test them on some gases...
                          • The MQxx:
                            • MQ2: good result on smoke
                            • MQ135 good result on CO2
                              The others I'm not yet able to give any opinion.

                          z-wave - Vera -> Domoticz
                          rfx - Domoticz <- MyDomoAtHome <- Imperihome
                          mysensors -> mysensors-gw -> Domoticz

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                          • P Offline
                            P Offline
                            promy
                            wrote on last edited by promy
                            #88

                            Great project!
                            I hooked up an MQ135 (sensor on a little pcb with (i think) smd resistor 102 (=1K ohm) between gnd and B )
                            The readings are however all over the place (135ppm to 1332ppm), so i think i need to calibrate. The raw reading is alwas in the range 71-80 (inside).

                            I know i have to get it outside and the reading should be 392 or 399 ppm but i am unsure what var i should change?
                            The sketch says mq135_ro (this has to be tuned 10K Ohm) but that does not seem to be used in the calculations?

                            I tried the sensor outside, but I am getting some different readings: the measured value changes from 59 to 82. The mq135_ro (i suppose that's the suggested ro) from 3081.00 to 81416 (does not go linear with the measured value?
                            The sensor was heated for more than 24h and then moved outside (started measuring after 5min, in windy conditions)

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                            • jeylitesJ Offline
                              jeylitesJ Offline
                              jeylites
                              wrote on last edited by jeylites
                              #89

                              I'm using the standard Smoke sketch from Mysensor library and it seem to be crashing MySensor plugin on Vera edge. Below is a snapshot of the problem. Any ideas?

                              Screen Shot 2015-05-07 at 8.13.01 AM.png

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                              • korttomaK Offline
                                korttomaK Offline
                                korttoma
                                Hero Member
                                wrote on last edited by korttoma
                                #90

                                I take it that you are talking about the Air_Quality sketch right? The problem is that you do not have the device files for this kind of sensor in your Vera MySensor plugin. There is another thread that contains the files, I'll see if I can find it.

                                Edit: Found the thread -> http://forum.mysensors.org/topic/661/assistance-needed-completing-gas-air-quality-sensor

                                • Tomas
                                jeylitesJ 1 Reply Last reply
                                0
                                • korttomaK korttoma

                                  I take it that you are talking about the Air_Quality sketch right? The problem is that you do not have the device files for this kind of sensor in your Vera MySensor plugin. There is another thread that contains the files, I'll see if I can find it.

                                  Edit: Found the thread -> http://forum.mysensors.org/topic/661/assistance-needed-completing-gas-air-quality-sensor

                                  jeylitesJ Offline
                                  jeylitesJ Offline
                                  jeylites
                                  wrote on last edited by jeylites
                                  #91

                                  @korttoma

                                  I'm going to try experiment tomorrow... Thank you!

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                                  • epierreE epierre

                                    Air Quality Index is a combination of several sensors values:

                                    • sulfur dioxide (SO2) MQ136 / (avoid:2SH12 no datasheet)
                                    • nitrogen dioxide (NO2) MiCS-2710 MiCS-2714 MICS-6814
                                    • carbon monoxide (CO) MQ-7 MiCS-5525 TGS2442 MICS-6814
                                    • ozone (O3) MQ131 MICS-2610 MICS-2614
                                    • Particles concentration: PM2.5 and PM10 (SamYoung DSM501, Shinyei_PPD42NS, avoid: Sharp_GP2Y1010AU)

                                    Additional gases can be interesting to track:

                                    • CO2 MH-Z14

                                    Current work being done:

                                    • manage default Ro once
                                    • take into account humidity
                                    • manage to get proper values from TGS2600
                                    • possibility to have a push if a value goes up too quick (for deadly gases even without calibration)

                                    What is done:

                                    • remove powerdown to keep heaters on
                                    • add a five minute pre-heat on each startup
                                    • removed the powerdown
                                    • 2SH12 datasheet doesn't exist

                                    WARNING: all sensors differs even within the same reference, a calibration has to be done each time. Do not rely upon a sketch result with deadly gases.

                                    Working sketch in 1.4/1.5:

                                    • https://github.com/empierre/arduino/blob/master/MQv01dgi_1_4.ino (for a Mega, MQ2, MQ6, MQ131, MQ136, MQ138, TGS2600, TGS2602, HCHO, Barometer BMP085, DHT11)
                                    • https://github.com/empierre/arduino/blob/master/AirQuality-CO-NO2-NH3.ino for MICS-6814
                                    • https://github.com/empierre/arduino/blob/master/CO2-MH-Z14.ino
                                    • https://github.com/empierre/arduino/blob/master/DustSensor_SamYoung_DSM501.ino
                                    • https://github.com/empierre/arduino/blob/master/DustSensor_Shinyei_PPD42NS.ino
                                    J Offline
                                    J Offline
                                    jroseastro
                                    wrote on last edited by
                                    #92

                                    @epierre thank you for sharing this code - your work is stellar. I'm working with a team of three other people to build a payload for a near space weather balloon launch in a couple of weeks.

                                    We're using the MQ131 Ozone Gas Sensor and your code has been quite useful to us. One question though, when our data logger reads the sensor we're getting a single number value. We're not exactly sure what that number means. Could you help explain what we're seeing? Are we getting a ppb number? ppm? Or something else altogether?

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                                    • epierreE Offline
                                      epierreE Offline
                                      epierre
                                      Hero Member
                                      wrote on last edited by
                                      #93

                                      @jroseastro hello, first of all the MQ series are not so precise as that, use it for a test run, but for serious purpose please consider something better and with calibration.

                                      Ozone is quite chalenging, if you go very high, since the MQ nead heating to work, it will drain fast your batteries.

                                      For any sensor always refer to the datasheet.

                                      MQ131 is given from 5 to 100 ppb (reason you get only a single value) if you use the provided calibration sheet. So the result is the one from the curve. We've had a discussion not yet settled with @hek about units and this is why I've not put it, but maybe I should uniformize everything in ppm since this is the most prevalent value used.

                                      Also the datasheet says you need 6V to heat it, so you cannot heat it from the arduino except with a step up (not that good) or an external power source (best) with a voltage regulator.

                                      z-wave - Vera -> Domoticz
                                      rfx - Domoticz <- MyDomoAtHome <- Imperihome
                                      mysensors -> mysensors-gw -> Domoticz

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                                      • epierreE Offline
                                        epierreE Offline
                                        epierre
                                        Hero Member
                                        wrote on last edited by epierre
                                        #94

                                        I'm now testing the MICS-6814 (3 sensors in one) given for :
                                        Carbon monoxide CO 1 -1000ppm
                                        **Nitrogen dioxide NO2 0.05 –10ppm **
                                        Ethanol C2H5OH 10 –500ppm
                                        Hydrogen H2 1 –1000ppm
                                        Ammonia NH3 1 –500ppm
                                        Methane CH4 >1000ppm
                                        Propane C3H8 >1000ppm
                                        Iso-butane C4H10 >1000ppm

                                        Datasheet maionly speaks on CO, NO2 and NH3:
                                        http://www.seeedstudio.com/wiki/images/1/10/MiCS-6814_Datasheet.pdf

                                        Here is are scripts:
                                        http://www.seeedstudio.com/wiki/Grove_-_Multichannel_Gas_Sensor

                                        http://www.seeedstudio.com/wiki/images/1/10/MiCS-6814_Datasheet.pdf

                                        Some readings:

                                        The concentration of NH3 is 0.99 ppm
                                        The concentration of CO is 1.20 ppm
                                        The concentration of NO2 is 0.15 ppm
                                        The concentration of C3H8 is 1000.04 ppm
                                        The concentration of C4H10 is 999.98 ppm
                                        The concentration of CH4 is 2991.14 ppm
                                        The concentration of H2 is 1.09 ppm
                                        The concentration of C2H5OH is 1.40 ppm
                                        

                                        I guess I'll make a script soon...

                                        z-wave - Vera -> Domoticz
                                        rfx - Domoticz <- MyDomoAtHome <- Imperihome
                                        mysensors -> mysensors-gw -> Domoticz

                                        VirV 1 Reply Last reply
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                                        • B Offline
                                          B Offline
                                          bhavika
                                          wrote on last edited by bhavika
                                          #95

                                          I think MQ131 need 24 hours preheating time.Because of preheating time it will be costly. and for MiCS 6814 how do you calculate or measured other values of gases?? Because sensor's data sheet it hard to understand

                                          epierreE 1 Reply Last reply
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