Well the replacement regulator datasheet says that pin 5 its not connected to anything so I'm assuming that it doesn't matter. With regard to the PCB, I don't know the answer to that and didn't really consider that. I don't have the actual schematic but my understanding is that all Arduino Mini Pro's are made from the same schematic so if so, pin 4 per the schematic is "bypass" and is not attached to anything on the PCB.