You can put 100uf on each even 200uf would not be able to handle only one tx, so..
but you need them at least for coin cells.
you would need more capa to handle tx..but the more capa the more time they take for recharging, and the recharging if big, increase internal res of the coin cell and that's not so good too; to prevent this that would need a current resistor limiter..etc a whole balance!
On mine for instance, I have 100uF for coincell, 100uF for PIR and 86uf on radio. Fresh varta coincell 3.02V, after multiple presentation tx 2.85V if I remember, not so bad. but that's an homemade pcb.
Another notes, it's better to use ceramic capacitor (because of leakage, if you want to optimize), and better smd, but that's not your case I think.
The final version of the boards contains few notable improvements
Removed the PCB under the ESP8266 antenna. The previous design had PCB + Ground Plane, which resulted in VERY low reception. It worked just few meters away from the router.
Removed the Temperature Probe - On the one hand - it does not really measure real temperature, on the other hand it populates the Single Analog port, and makes it unavailable for other usages
Added place for an optional LDR (in case the Analog port is not used - one could add an LDR for added value)
The connection between GPIO 16 and RST (Deep Sleep) is not bridged via a 0603 0ohm resistor (jumper). Depending on application it may be enabled or not
Added a Power 5V line. That is - controlled via a SOT232 mosfet and one GPIO. This way you can connect power hungry modules and then turn them on or off. There are small mosfets rated ~ 2-3 amps for couple of cents.
The big 12mhz crystal for the CH340G was replaced by a small patch ceramic oscillator to save space
Added an additional mounting hole
Added additional test pads for the unused GPIOs
Added one Diode in series with the power to the WS2812B LED. It turned out, when powered directly via a USB Battery bank, the voltage can be 5.30-5.40v. And apparently WS2812B, does not light if VIN is > 5.15V. So putting a generic small Diode would drop 0.3-0.4V
Here is how the latest design looks like